Summary
We have grafted butyl rubber from PVC under a variety of conditions. The physical-mechanical properties of these graft copolymers have been examined both before and after extraction with hexane of the ungrafted butyl rubber. We have found a significant increase in the tensile strength of these materials upon S2Cl2 treatment (curing) in THF solution. This increase was observed even with unextracted copolymers. Electron micrograph studies suggest that curing causes an aggregation of the butyl rubber segments into crosslinked domains.
Similar content being viewed by others
Reference
K. B. ABBAS and N. G. THAME: J. Poly. Sci., Chem. Ed. 13, 59 (1975)
N. G. GAYLORD and A. TAKAHASHI: Polymer Letters, 8, 361 (1970)
J. P. KENNEDY and D. L. DAVIDSON: J. Poly. Sci., Chem. Ed. 14, 153 (1976)
J. P. KENNEDY and D. L. DAVIDSON: J. Appl. Poly. Sci. Appl. Polym. Symp. 30, 13 (1977)
N. G. THAME, R. D. LUNDBERG and J. P. KENNEDY, J.: Polym. Sci., Al, 10, 2507 (1972)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Trivedi, P.D., Ambrose, R.J. Tensile properties and morphology of S2Cl2 treated PVC-g-butly rubber. Polymer Bulletin 1, 389–395 (1979). https://doi.org/10.1007/BF00284408
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00284408