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The synthesis of an isobutylene-α-methylstyrene block copolymer with olefinic head-group: (CH3)2C=CHCH2-PIB-b-PαMeSt

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Summary

The title head-functionalized block copolymer was synthesized by first preparing a polyisobutylene carrying a (CH3)2C=CH2-head-group and -Cl end-group, and subsequently starting the block copolymerization of α-methylstyrene from the -Cl terminus.

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References

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Author notes

  1. S. Y. Huang

    Present address: American Cyanamid Co., 06904, Stamford, Conn.

Authors and Affiliations

  1. Institute of Polymer Science, University of Akron, 44325, Akron, Ohio, USA

    Joseph P. Kennedy, S. Y. Huang & Robert Alan Smith

Authors
  1. Joseph P. Kennedy
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  2. S. Y. Huang
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  3. Robert Alan Smith
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7th in the series: Cationic Polymerization with Boron Halides.

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Kennedy, J.P., Huang, S.Y. & Smith, R.A. The synthesis of an isobutylene-α-methylstyrene block copolymer with olefinic head-group: (CH3)2C=CHCH2-PIB-b-PαMeSt. Polymer Bulletin 1, 371–376 (1979). https://doi.org/10.1007/BF00284405

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  • DOI: https://doi.org/10.1007/BF00284405

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