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Application of equation-of-state theories to some polymeric liquids

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Summary

Density-temperature data of some aliphatic block and branched α,ω-dihydroxy-polyesterethers, of some aliphatic α,ω-dihydroxy-polyesters, -polyethers,-polycarbonates and of 1,2,3-propanetriyl triacetate fit satisfactorily the equations of state of Flory's1–3 and Lattice Fluid4–6 theories. Characteristic specific volumes (or densities) and temperatures have been determined. Characteristic pressure of 1,2,3-propanetriyl triacetate and of α,ω-dihydroxy-polyoxyethylene have been calculated from these values and from literature compressibility data.

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Edelman, A., Fradet, A. Application of equation-of-state theories to some polymeric liquids. Polymer Bulletin 19, 555–560 (1988). https://doi.org/10.1007/BF00283101

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