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Effect of temperature on the solution properties in 2-ethoxyethanol of statistical copolymers of methacrylic acid and methyl methacrylate

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Summary

The temperature dependence of the second virial coefficient and intrinsic viscosity of statistical copolymers of methyl methacrylate and methacrylic acid in 2-ethoxyethanol was investigated. It was found that the θ-temperatures of copolymers are outside the temperature range given by the θ-values for poly(methacrylic acid) and poly(methyl methacrylate). Their dependence on the copolymer composition has a discontinuity. Simple theoretical considerations have shown that this behaviour may be expected with copolymers composed of monomer units dissolving, respectively, with absorption and evolution of heat.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, CS-162 06, Prague 6, Czechoslovakia

    Jiří Horský, Vladimír Petrus & Miloslav Bohdanecký

Authors
  1. Jiří Horský
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  2. Vladimír Petrus
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  3. Miloslav Bohdanecký
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Horský, J., Petrus, V. & Bohdanecký, M. Effect of temperature on the solution properties in 2-ethoxyethanol of statistical copolymers of methacrylic acid and methyl methacrylate. Polymer Bulletin 17, 551–556 (1987). https://doi.org/10.1007/BF00283092

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  • DOI: https://doi.org/10.1007/BF00283092

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