Skip to main content
SpringerLink
Log in

Preparation of a chelating poly(β-diketone) resin from poly(vinyl alcohol) and its use in the reversible complexing of metal ions

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

A water-insoluble poly (β-diketone) chelating resin has been prepared by the controlled oxidation of poly(vinyl alcohol) with chromic acid. The polymer forms stable complexes with divalent and trivalent cations, such as Co+2, Cu+2, Mn+2, Ni+2, Fe+3, Au+3, and UO2 +2, and removes them completely from dilute aqueous solution. The ions may be recovered quantitatively from the resin complex by elution with dilute aqueous acid and the resin is reusable

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • R. G.Bayless, D. D.Emrich and R. L.Hart: Ger. Offen. 2,034,658 (28 Jan. 1971); Chem. Abstr. 74, 142971u (1971)

  • H.Hartel and I. U.Nebel: Neth, Appl. 6,516,487 (20 June 1966); Chem. Abstr. 65, 18780e (1966)

  • R. Hering: J. Prakt. Chem. 14, 285 (1961)

    Google Scholar 

  • R. Hering: Z. Chem. 5, 194 (1965)a

    Google Scholar 

  • R.Hering: Ger. (East) 42,086 (25 Oct. 1965b)

  • R. Hering: Z. Chem. 5, 402 (1965)c

    Google Scholar 

  • N.Hojo: J. Fac. Textile Sericult., Shinshu Univ., Ser. C, No. 5, (1958); Chem. Abstr. 53, 21351b (1959)

  • R. A.Mock, R. C.Calktns and C. A.Marshall: U.S. 2,980,607 (18 Apr. 1961); Chem. Abstr. 55, 17953f (1961)

  • S. Okamura and T. Motoyama: Kyoto Daigaku Nippon Kagakuseni Kenkyusho Koenshu 16, 43 (1959); Chem. Abstr. 54, 7531a (1960)

    Google Scholar 

  • J. R.Parrish: Chemistry and Industry, 386-(1955)

  • J. P. Riley and D. Taylor: Anal. Chim. Acta 40, 479 (1968)a

    Google Scholar 

  • J. P.Riley and D.Taylor: ibid. Anal. Chim. Acta 41, 175 (1968)b

  • T. Saigusa and R. Oda: J. Chem. Soc. Japan, Ind. Chem. Sect. 57, 950 (1954); Chem. Abstr. 49, 11317c (1955)

    Google Scholar 

  • T.Such and H. F.Davison: Brit. 1,059,569 (22 Feb. 1967): Chem. Abstr. 66, 81907p (1967)

  • Y. Trudelle and J. Neel: Compt. Rend. 258, 4267, 4542 (1964)

    Google Scholar 

  • Y.Trudelle and J.Neel: ibid. Compt. Rend. 260, 1950 (1965)

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, California State University, Dominguez Hills, 90747, Carson, California, USA

    Solomon Marmor & Getachew Kidane

Authors
  1. Solomon Marmor
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Getachew Kidane
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Marmor, S., Kidane, G. Preparation of a chelating poly(β-diketone) resin from poly(vinyl alcohol) and its use in the reversible complexing of metal ions. Polymer Bulletin 1, 239–242 (1978). https://doi.org/10.1007/BF00283077

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00283077

Keywords

Search

Navigation