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Polymerization via zwitterions. 22. Alternating copolymerization of 2-acryloxypropionic acid with cyclic phosphorus compounds

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Summary

Alternating copolymerization of 2-acryloxypropionic acid (APA) as a new MN with two MN monomers of phosphorus containing ethylene phenyl phosphonite (EPO) and ethylene phenyl phosphite (EPI) have been disclosed. Copolymerizations took place without added catalyst to produce 1∶1 alternating copolymers of APA-EPO and of APA-EPI. The structures of the copolymers were determined by IR and NMR spectroscopy, elemental analyses, as well as the identification of the alkaline hydrolysis products. The copolymerizations were explained in terms of a mechanism of zwitterion intermediates involving a hydrogen transfer process.

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Authors and Affiliations

  1. Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, 606, Kyoto, Japan

    Takeo Saegusa, Shiro Kobayashi & Jun-ichi Furukawa

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  1. Takeo Saegusa
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  2. Shiro Kobayashi
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  3. Jun-ichi Furukawa
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Saegusa, T., Kobayashi, S. & Furukawa, Ji. Polymerization via zwitterions. 22. Alternating copolymerization of 2-acryloxypropionic acid with cyclic phosphorus compounds. Polymer Bulletin 1, 171–176 (1978). https://doi.org/10.1007/BF00283066

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  • DOI: https://doi.org/10.1007/BF00283066

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