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Polymer-supported aza-15-crown-5 as effective catalyst for phase-transfer reactions

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Summary

Immobilized aza-15-crown-5 were prepared by the reaction of chloromethylated polystyrene resin with N-(2-hydroxyethyl)-aza-15-crown-5. These polymer-supported crowns were very effective catalysts of nucleophilic substitution reactions carried out under the conditions of the two-phase (L-S) or three-phase (L-S-L) catalysis.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, CS-162 06, Prague 616, Czechoslovakia

    B. Valter, V. Janout, H. Hrudková & P. Čefelín

  2. Physico - Chemical Institute, Academy of Sciences of Ukrainian SSR, Chernomorskaya doroga 86, SU-270 080, Odessa, USSR

    N. G. Lukyanenko, S. S. Basok & E. Yu. Kulygina

Authors
  1. B. Valter
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  2. V. Janout
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  3. H. Hrudková
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  4. P. Čefelín
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  5. N. G. Lukyanenko
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  6. S. S. Basok
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  7. E. Yu. Kulygina
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Valter, B., Janout, V., Hrudková, H. et al. Polymer-supported aza-15-crown-5 as effective catalyst for phase-transfer reactions. Polymer Bulletin 22, 261–264 (1989). https://doi.org/10.1007/BF00282850

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  • DOI: https://doi.org/10.1007/BF00282850

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