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The electric conductivity of poly(ethyl vinyl ketone) film reacted with phosphoryl chloride

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Summary

The reaction of poly (ethyl vinyl ketone) with active chlorides in petroleum ether was followed by the electric conductivity measurement. Phosphoryl chloride was found to be an effective reagent to produce a highly conjugated system with an apparent specific conductivity of the order of 10−2 Ω−1cm−1 in petroleum ether. The reaction temperature seems to be important for the electric conductivity of the product, the higher the reaction temperature, the lower the electric conductivity of the reacted film.

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References

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Authors and Affiliations

  1. Centro de Investigaciones sobre Polimeros y Materiales, Universidad de Sonora, Rosales y Esq. Boulevard Transversal, Hermosillo, Sonora, Mexico

    Takeshi Ogawa, Ruben Cedeño & Motomichi Inoue

Authors
  1. Takeshi Ogawa
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  2. Ruben Cedeño
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  3. Motomichi Inoue
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Ogawa, T., Cedeño, R. & Inoue, M. The electric conductivity of poly(ethyl vinyl ketone) film reacted with phosphoryl chloride. Polymer Bulletin 2, 275–280 (1980). https://doi.org/10.1007/BF00282286

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  • DOI: https://doi.org/10.1007/BF00282286

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