Summary
This note deals with the preparation of ultra-high strength polyethylene filaments by suspension spinning and subsequent hot-drawing at 148 °C. Suspension spinning involves the flow of stabilized suspensions of high molecular weight polyethylene powder in a solvent mixture through a long heated tube. In the tube, which acts as the spinning apparatus, the polyethylene is dissolved after which the polymer solution is spun in air. Under appropriate conditions of spinning and hot-drawing monofilaments were produced with a tensile strength at break of 3.8 GPa and a Young's modulus of 124 GPa.
Similar content being viewed by others
References
P. Smith, P.J. Lemstra, B. Kalb, A.J. Pennings, Polym. Bull., 1, 733 (1979).
B. Kalb, A.J. Pennings, J. Mater. Sci., 15, 2584 (1980).
J. Smook, M. Flinterman, A.J. Pennings, Polym. Bull., 2, 775 (1980).
J. Smook, A.J. Pennings, J. Mater. Sci., in press.
P.G. de Gennes, J. Chem. Phys., 55, 572 (1971).
A.J. Pennings, H.C. Booy, J.H. Duysings, IUPAC Leìden, I.U.P.A.C., Leiden, 1, 263 (1970).
H. Giesekus, Rheol. Acta, 5, 239 (1966).
J. Le Blanc, Rubber Chem. Techn., 54, 905 (1981).
J.L. White, Appl. Polym. Symp., 20, 155 (1973).
J.A. Brydson, Flow Properties of Polymer Melts, George Godwin, Ltd., London, 78 (1981).
J.S. Stephens, J. Pharm. Pharmacol., 23, 774 (1971).
K.A. Narh, P.J. Barham, A. Keller, Macromolecules, 15, 464 (1982).
A. Ziabicki, Fundamentals of Fibre Formation, J. Wiley and Sons, London, 62 (1976).
J. Smook, A.J. Pennings, Polym. Bull., 9, 75 (1983).
E.W. Fischer, Pure Appl. Chem., 50, 319 (1978).
R.B. Williamson, W.F. Busse, J. Appl. Phys., 38, 4187 (1967).
A. Peterlin, D.T. Turner, J. Polym. Sci., Polym. Lett., 3, 517 (1965).
G. Capaccio, T.A. Crompton, I.M. Ward, Polymer, 17, 644 (1980).
J. Smook, A.J. Pennings, J. Appl. Polym. Sci., 27, 2209 (1982).
D.E. Hanson, Polym. Eng. Sci., 9, 405 (1969).
F. Bueche, J. Chem. Phys., 48, 4781 (1968).
U. Reinehr, J. Dross, T. Herbertz, German Patent. no. 2901-860 (1979).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Smook, J., Pennings, A.J. Suspension spinning of ultra-high molecular weight polyethylene. Polymer Bulletin 10, 291–297 (1983). https://doi.org/10.1007/BF00281938
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00281938