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Polymerization of vinylchloride by t-butylmagnesiumchloride

2. Structure of oligomers by C-13 NMR

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Summary

Vinylchloride has been polymerized in THF by t-butylmagnesiumchloride as an initiator. Saturated oligomers of DP=1−3 have been prepared and analyzed by joint HPLC and C-13 nmr spectroscopy. The structure of the oligomers confirm a regular head-to-tail enchainment of the monomer during initiation and propagation.

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References

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Authors and Affiliations

  1. Universität (GH) Duisburg, FB 6 Physikalische Chemie, D-4100, Duisburg 1, Federal Republic of Germany

    K. -F. Elgert & R. Kosfeld

Authors
  1. K. -F. Elgert
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  2. R. Kosfeld
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Elgert, K.F., Kosfeld, R. Polymerization of vinylchloride by t-butylmagnesiumchloride. Polymer Bulletin 10, 175–181 (1983). https://doi.org/10.1007/BF00275853

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  • DOI: https://doi.org/10.1007/BF00275853

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