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Chemical modification of poly(vinyl chloroformate) and of its copolymers using phase transfer catalysis

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Abstract

The chemical modification of poly(vinyl chloroformate) and of its copolymers with compounds containing labile hydrogen atoms like amines, phenols, alcohols and 2-oxazolidone as well as with potassium cyanide and potassium fluoride has been investigated. Phase transfer catalysis conditions lead to soluble modified polymers with good substitution yields.

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Authors and Affiliations

  1. Laboratoire de Chimie Macromoléculaire associé au CNRS, Collège de France, 11 place Marcelin Berthelot, F-75231, Paris Cédex 05, France

    Sylviane Boivin, Abderrahmane Chettouf, Patrick Hemery & Sylvie Boileau

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  1. Sylviane Boivin
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  2. Abderrahmane Chettouf
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  3. Patrick Hemery
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  4. Sylvie Boileau
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Boivin, S., Chettouf, A., Hemery, P. et al. Chemical modification of poly(vinyl chloroformate) and of its copolymers using phase transfer catalysis. Polymer Bulletin 9, 114–120 (1983). https://doi.org/10.1007/BF00275577

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  • DOI: https://doi.org/10.1007/BF00275577

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