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Studies on the cationic polymerization of styrene by using perdeuterated monomer

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Summary

Perdeuterated styrene was polymerized by TiCl4 and EtAlCl2 in toluene at −78°C and the resultant polymer was examined for the terminal group containg protons by using 1h NMR spectroscopy. The polymer prepared by TiCl4 was found to contain 0.64 of toluene fragments per a polymer molecule and a similar amount of CHD2-group. The ratios of kM/kP and kS/kP were estimated to be 0.0228 and 0.0035, respectively. Similar results were obtained for the polymerization initiated with EtAlCl2

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan

    Koichi Hatada, Tatsuki Kitayama & Heimei Yuki

Authors
  1. Koichi Hatada
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  2. Tatsuki Kitayama
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  3. Heimei Yuki
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Additional information

The authors are grateful to Professor T. Higashimura of Kyoto University for his helpful discussion and also to Mrs. F.Yano for her clerical assistance in preparing the manuscript.

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Hatada, K., Kitayama, T. & Yuki, H. Studies on the cationic polymerization of styrene by using perdeuterated monomer. Polymer Bulletin 2, 15–19 (1980). https://doi.org/10.1007/BF00275547

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  • DOI: https://doi.org/10.1007/BF00275547

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