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Thermochemistry of model curing reactions of epoxy resins

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Summary

The heats of reaction of phenylglycidyl ether and N,N-methylglycidylaniline as model systems for two different types of epoxy resins with primary and secondary amine were determined. In all cases the heat of reaction was found to be dependent on the ratio of the reactant components. This dependence is probably due to the formation of various complexes via a hydrogen bond. It was also found that, while the heats of reaction of phenylglycidyl ether with primary and secondary amine are the same, the heats of reaction of N,N-methylglycidylaniline with primary and secondary amine differ significantly from each other.

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References

  1. H.J.Booss, Angew.Makromol.Chem.45, 65 (1975)

    Google Scholar 

  2. K.Horle, J.Mita, H.Kambe, J.Polym.Sci.A-1, 8, 1357 (1970)

    Google Scholar 

  3. C.H.Klute, W.Wiehmann, J.Appl.Polym.Sci. 5, 86 (1961)

    Google Scholar 

  4. V.P.Kuzněcova, E.A.Mirošničenko, A.J.Zelenickij, G.V.Rakova, J.A.Lebeděv, N.S.Jenikolopjan, Dokl.Akad.Nauk SSSR 225, 605 (1975)

    Google Scholar 

  5. V.P.Kuzněcova, E.A.Mirošničenko, A.J.Zelenickij, G.V.Rakova, J.A.Lebeděv, N.S.Jenikolopjan, Dokl.Akad.Nauk SSSR 226, 1109 (1975)

    Google Scholar 

  6. V.P.Kuzněcova, L.V.Vladimirov, E.A.Mirošničenko, A.J.Zelenickij, G.V.Rakova, E.T.Olejnik, J.A.Lebeděv, N.S.Jenikolopjan, Dokl.Akad.Nauk SSSR 231, 1162 (1976)

    Google Scholar 

  7. C.A.Arutjunjan, A.O.Tonojan, S.P.Davtjan, B.A.Rozenberg, N.S.Jenikolopjan, Z.Fiz.Chim. 48, 2896 (1974)

    Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, CS-162 06, Prague 6, Czechoslovakia

    Vladimir Špaček, Jan Biroš & Julius Pouchlý

  2. Research Institute of Synthetic Resins and Lacquers, CS-53207, Pardubice, Czechoslovakia

    Ivan Dobáš

Authors
  1. Vladimir Špaček
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  2. Jan Biroš
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  3. Julius Pouchlý
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  4. Ivan Dobáš
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Additional information

On leave of absence from the Research Institute of Synthetic Resins and Lacquers, Pardubice

The authors thank Dr Š.Štokrová, Dr S.Pokorný and Dr Š.Podzimek, Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, Prague, for the analysis of the reaction products.

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Špaček, V., Biroš, J., Pouchlý, J. et al. Thermochemistry of model curing reactions of epoxy resins. Polymer Bulletin 15, 439–443 (1986). https://doi.org/10.1007/BF00265726

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  • DOI: https://doi.org/10.1007/BF00265726

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