Summary
Simulations of a conceptually simple model for free-radical cross-linking polymerization have been performed in relation to experimental indications for (temporary) microgel particles. Many qualitative features ascribed to microgels show up in the simulation. In particular this model yields qualitative agreement with experiments on the conversion dependence of the number of pendant double bonds.
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Boots, H.M.J., Pandey, R.B. Qualitative percolation study of free-radical cross-linking polymerization. Polymer Bulletin 11, 415–420 (1984). https://doi.org/10.1007/BF00265480
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DOI: https://doi.org/10.1007/BF00265480