Summary
Three new phenothiazine-containing electrono-donor monomers: methacryloyl-2′-hydroxyethyl-2-(N-phenothiazinyl)propionate (i) acryloyl-2′-hydroxyethyl-2-(N-phenothiazinyl) propionate (ii) and 2-(N-phenothiazinyl) propionic acid vinyl ester (iii) were synthesized and radically polymerized. The ionization potentials of poly(i), poly(iii) and of the model for the structural unit of the acrylic polymers: acetyl-2′-hydroxyethyl-2-(N-phenothiazinyl) propionate determined with two small acceptors were discussed in terms of sterical hindrances.
Similar content being viewed by others
References
C.I.Simionescu and V.Percec, J.Polym.Sci., Polym.Symp., 67, 43 (1980); ibidem Progr.Polym.Sci., in press
C.I.Simionescu and V.Percec, J.Polym.Sci., Polym.Chem.Ed., 17, 2287 (1979); ibidem J.Polym.Sci., Polym.Symp., Polym.Bull., 2, 51 (1980); ibidem Polym.Bull., 2, 427 (1980)
C.I.Simionescu and V.Percec, Polym.Bull., submitted
C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 4, 623 (1981)
W.Reppe, Ann., 601, 81 (1956)
H.Kamogawa, J.M.Larkin, K.Toei and H.G.Kaasidy, J.Polym. Sci., A 2, 3603 (1964)
E.Gipstein, W.A.Hewett and O.U.Need, J.Polym.Sci., A-1, 8, 3285 (1970)
H.Kamogawa, J.Polym.Sci., A-1, 10, 95 (1972)
M.Litt and J.W.Summers, J.Polym.Sci., Polym.Chem.Ed., 11, 1339 (1973)
P.Hyde, L.J.Kricka, A.Ledwith and K.C.Smith, Polymer, 15, 387 (1974)
S.Watarai, Polym.Bull., 3, 291 (1980)
J.M.Pearaon, J.Macromol.Sci., Chem., A9, 1029 (1975)
G.Manecke, Angew.Makromol.Chem., 4/5, 26 (1968)
R.Knoesel, B.Gebus and J.Parrod, C.R.Acad.Sci. (Paris) 267, 727 (1969); ibidem Angew.Makromol.Chem., Bull.Soc.Chim.Fr., 1969, 290; ibidem Bull.Soc.Chim.Fr., 1971, 4471
R. Knoesel, B. Gebus, J.P. Roth and J. Parrod, Bull.Soc.Chim. Fr., 1969, 294
B.Gebus and R.Knoesel, Makromol.Chem., 175, 1439 (1974)
W.Klöpffer and W.Willicks, Makromol.Chem., 115, 156 (1968)
M.Litt and J.W.Summers, J.Polym.Sci., Polym.Chem.Ed., 11, 1359 (1973); ibidem J.Polym.Sci., Polym.Chem.Ed., 11, 1379 (1973)
J.M.Pearaon, S.R.Turner and A.Ledwith in “Molecular Associations”, R.Foster Ed., Academic Press, 1979, vol.2, p.79
C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 3, 535 (1980)
C.I.Simionescu, A.Natansohn and V.Percec, Polym.Bull., 3, 543 (1980)
N.L.Smith, J.Organic Chem., 15, 1125 (1950)
R.S.Becker and E.Chen, J.Chem.Phys., 45, 2403 (1966)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Percec, V., Tocaciu, D.C., Man, E. et al. New phenothiazine-containing monomers and polymers. Polymer Bulletin 5, 233–238 (1981). https://doi.org/10.1007/BF00265170
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00265170