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Novel sulfur-containing telechelics with alternating aliphatic-aromatic structure units

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Summary

Radical polyaddition of 1,3-dimercaptobenzene onto 1,5-hexadiyne yields sulfur containing polyenolthioethers. By using the method of unstoichiometric ratio not only the molar masses but also the functional end groups of the products can be controlled. The telechelics synthesized are soluble in common solvents such as benzene, toluene and chloroform.

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Authors and Affiliations

  1. Lehrstuhl für Makromolekulare Chemie I, Universität Bayreuth, Postfach 101251, D-8580, Bayreuth, Federal Republic of Germany

    Oskar Nuyken

  2. Lehrstuhl für Makromolekulare Stoffe, TU München, Lichtenbergstraße 4, D-8046, Garching, Federal Republic of Germany

    Florian Siebzehnrübl

Authors
  1. Oskar Nuyken
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  2. Florian Siebzehnrübl
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Additional information

We wish to thank the DFG (Nu 23/10) for financial support.

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Nuyken, O., Siebzehnrübl, F. Novel sulfur-containing telechelics with alternating aliphatic-aromatic structure units. Polymer Bulletin 19, 371–375 (1988). https://doi.org/10.1007/BF00263939

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  • DOI: https://doi.org/10.1007/BF00263939

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