Summary
We have applied a newly developed time resolved Fourier transform infrared spectroscopy to follow microstructural changes in two semicrystalline polymers with time resolution in the order of milliseconds. This is the first demonstration of a spectroscopic technique which is capable of measuring structural changes at the segmental level and relating them to macroscopic changes measured by dynamical mechanical spectroscopy.
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Lasch, J.E., Masaoka, T., Burchell, D.J. et al. Polymer deformation studies by time resolved Fourier transform infrared spectroscopy. Polymer Bulletin 10, 51–55 (1983). https://doi.org/10.1007/BF00263238
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DOI: https://doi.org/10.1007/BF00263238