Summary
Fast spectroscopy experiments have been performed upon the photoinitiation process of a vinyl polymerization with the benzophenone-amine derivative system. The rate constants of the processes in the excited states have been determined. The results make it possible to discuss the rate constant of the polymerization and to deduce the efficiency of the initiating radicals.
Similar content being viewed by others
References
J.P.FOUASSIER and A.MERLIN J. of Photochem. 12, 17 (1980) Canad.J. of Chem. 57, 2812 (1979)
J.FAURE,J.P.FOUASSIER,D.J. LOUGNOT and R. SALVIN Nouv. J. Chimie 1(1), 15, (1977)
A.V.BUETTNER,J.DEDINAS J.Phys. Chem. 75, 187, (1971)
J.B.GUTTENPLAN,S.G.COHEN Tetrahedron Lett. 2163 (1972)
M.R.SANDNER,C.L.OSBORN,D.J.TRECKER J.Polym. Sci. 3173 (1972)
H.BLOCK,A.LEDWITH,A.R.TAYLOR Polymer 2, 271, 1971
A.MERLIN and J.P.FOUASSIER Makromol. Chem. in press
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Merlin, A., Lougnot, D.J. & Fouassier, J.P. The benzophenone-amine photoinitiator in vinyl polymerization. Polymer Bulletin 3, 1–6 (1980). https://doi.org/10.1007/BF00263198
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00263198