Skip to main content
SpringerLink
Log in

Rate of radical polymerization of N,N-dimethylaminoethyl methacrylate in cyclohexane

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

Dilatometric measurements of the rate of polymerization of N,N-dimethylaminoethyl methacrylate(DMAEMA) gave kp/k2 1/2=7.67×10−2 (mole. sec/l)1/2 at [DMAEMA]0 =2.000 M in cyclohexane at 60°C. The rate was proportional to the first order and 0.5 order of DMAEME and AIBN concentrations, respectively, in cyclohexane. The initial rate of polymerization varied little in organic solvents.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • BROWN,C.E.H. and VERDIN,D.:Trans. Faraday Soc.56,815(1960)

    Google Scholar 

  • EGOYAN,R.V., CABTON,L.M. and BEILERYAN,N.M.: Arm.Khim.Zh.32,520(1979a) Chem. Abstr.92,164367a(1980); ibid.,32,93(1979b) Chem. Abstr.91, 158189g (1979)

    Google Scholar 

  • EGOYAN,R.V.,GRIGORYAN,V.V. and BEILERYAN,N.M.: Arm. Khim. Zh.35,570 (1982) Chem. Abstr.97,182951u(1982)

    Google Scholar 

  • GERDVILITE,B.:Deposited Doc.,VINITI3784,417(1979) Chem. Abstr.94,140232t(1981)

  • RIDDICK,J.A. and TOOPS,E.E. “Organic Solvents” 2nd.ed.,Interscience, 1955

  • RUZIEV,R., NECHAEVA,A.V.,DZHALILOV,A.T.,TOPCHIEV,D.A. and KABANOV, V.A. :Uzb. Khim. Zh.1979,59 Chem. Abstr.91,39972x (1979)

  • VAN HOOK,J.P. and TOBOLSKY,A.V.: J. Am. Chem. Soc.80,779 (1958)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of New England, 2351, Armidale, N.S.W., Australia

    Kiyohisa Fujimori, Anthony S. Brown, Marion J. Costigan & Ian E. Craven

Authors
  1. Kiyohisa Fujimori
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Anthony S. Brown
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Marion J. Costigan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ian E. Craven
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fujimori, K., Brown, A.S., Costigan, M.J. et al. Rate of radical polymerization of N,N-dimethylaminoethyl methacrylate in cyclohexane. Polymer Bulletin 12, 349–352 (1984). https://doi.org/10.1007/BF00263151

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00263151

Keywords

Search

Navigation