Skip to main content
SpringerLink
Log in

Polymer-supported transition metal clusters

1. Copolymers containing tricobalt carbonyl clusters

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The synthesis of appropriate monomers bearing alkylidyne tricobaltnonacarbonyl cluster or sulfido tricobalt heptacarbonyl cluster is described. Organometallic copolymers are obtained by free-radical copolymerisation with other vinyl monomers. Direct metallation of macromolecules containing the dithioester or the thioamide functional groups was also studied. We show that the copolymerisation method is more convenient for the synthesis of pure materials containing a variable amount of definite cluster units. The potentiality of these new organometallic polymers with regard to homogeneous catalysis and for the modification of electrode surfaces is also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • HARAOUBIA R., BONNANS-PLAISANCE C., LEVESQUE G., Makromol. Chem., 182, 2409 (1981)

    Google Scholar 

  • HARAOUBIA R., LEVESQUE G., GRESSIER J.C., Makromol. Chem., 176, 2143 (1975)

    Google Scholar 

  • LEVESQUE G., HARAOUBIA R., BONNANS-PLAISANCE C., GRESSIER J.C., Makromol. Chem. in the press

  • MAHE C., These RENNES, 1982

  • MUETTERTIES E.L., J. Organomet. Chem., 200, 177 (1980)

    Google Scholar 

  • PATIN H., MIGNANI M., MAHE C., LE MAROUILLE J.Y., BENOIT A., GRANJEAN D., LEVESQUE G., J. Organomet. Chem. 208, C39 (1981)

    Google Scholar 

  • PATIN H., MIGNANI M., VAN HULLE, M.T., Tetrahedron Lett, 2441 (1979)

  • PITTMAN C.U., in “Polymer-supported Reactions in Organic Synthesis”, edited by P. Hodge and D.C. Sherrington, J. WILEY and Sons, New York, (1980).

    Google Scholar 

  • PITTMAN C.U, RYAN R.C., Chem. Tech., 8, 170 (1978)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Physico-chimie et Photochimie Organiques, Université du Maine, F-72017, Le Mans, France

    J. C. Gressier & G. Levesque

  2. Laboratoire de Chimie des Organométalliques, ERA CNRS N∘477, Université de Rennes, F-35042, Rennes, France

    H. Patin

Authors
  1. J. C. Gressier
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Levesque
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Patin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gressier, J.C., Levesque, G. & Patin, H. Polymer-supported transition metal clusters. Polymer Bulletin 8, 55–61 (1982). https://doi.org/10.1007/BF00263008

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00263008

Keywords

Search

Navigation