Summary
Derivatives of poly(oxyethylene) with chlorine and aldehyde functions have been prepared by chemical modification in an one-step and two-step reaction respectively with thionyl chloride and 4-hydroxy benzaldehyde in excellent yields. The functionality of these important intermediates has been investigated spectroscopically and demonstrated by chemical conversion of the terminal groups.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
ANZINGER, H. and MUTTER, M.: Polym. Bull. 6, 595 (1982)
BAYER, E., GRATHWOHL, P.A. and GECKELER, K.: Makromol. Chem., in press (1983)
GALIN, J.C., REMPP, P., and PARROD, J.: Compt. Rend. Acad. Sc. Paris 260, 5558 (1965)
GECKELER, K., GRATHWOHL, P.A., and BAYER, E.: Paper presented at the Internat. Symp. on Polymers in Organic Synthesis, Lyon, France (1982)
GECKELER, K.: Polym. Bull. 1, 427 (1979)
GECKELER, K. and BAYER, E.: Polym. Bull. 3, 347 (1980)
KENNEDY, J.P., CHANG, V.S., SMITH, R.A., and IVAN, B.: Polym. Bull. 1, 575 (1979)
KOPPENHOEFER, B.: Diplomarbeit, University of Tuebingen, 1976
MUTTER, M.: Tetrahed. Lett. 31, 2843 (1978)
ZHENG, H. et al.: in preparation (1983)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bayer, E., Zheng, H. & Geckeler, K. Functionalization of soluble polymers. Polymer Bulletin 8, 585–591 (1982). https://doi.org/10.1007/BF00262939
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00262939