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Micro and macroconformation of macromolecules

11. Glassy phase conformational analysis of semicrystalline and amorphous polymers by variable-temperature magic-angle spinning 13C NMR

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Summary

By variable temperature proton enhanced magic angle spinning 13C NMR below Tg individual conformational diads could be resolved for glassy phase segments in semicrystalline erythrodiisotactic poly(1,2-dimethyltetramethylene). An assignment based on γ-shift increments associated with antigauche conformational transitions is given. In addition an improved interpretation of conformational effects in the glassy phase solid state spectrum of amorphous threodiisotactic poly(1,2-dimethyltetramethylene) is presented.

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Authors and Affiliations

  1. Institut für Makromolekulare Chemie der Universität Freiburg, Hermann-Staudinger-Haus, Stefan-Meier-Straße 31, D-7800, Freiburg i.Br., Germany

    W. Gronski, M. Möller & H. -J. Cantow

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  1. W. Gronski
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  2. M. Möller
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  3. H. -J. Cantow
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Gronski, W., Möller, M. & Cantow, H.J. Micro and macroconformation of macromolecules. Polymer Bulletin 8, 503–510 (1982). https://doi.org/10.1007/BF00262928

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  • DOI: https://doi.org/10.1007/BF00262928

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