Summary
Pervaporation of ethanol-water mixture was examined on IPN membranes composed of hydrophilic polyurethane(PU) and hydrophobia polystyrene(PS). The IPN membranes showed preferential pervaporation of water over ethanol and revealed high permeation rate. As the content of hydrophobic PS was increased, the permeation rate decreased while the separation factor increased, indicating that the PS domains suppressed the swelling of the PU phase and reduced the plasticizing effect. The average diffusion coefficient, computed from the permeation rate and solubility, was highly dependent on the viscosity and concentration of the permeant in the membrane.
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References
H. Tanisugi and T. Kotaka, Polym. J., 16, 909 (1984)
H. Tanisugi and T. Kotaka, Polym. J., 17, 499 (1985)
P. Aptel, J. Cuny, J. Jozefowicz, G. Morel, and J. Neel, J. Appl. Polym. Sci., 16, 1061 (1972)
P. Aptel, J. Cuny, J. Jozefowicz, G. Morel, and J. Neel, J. Appl. Polym. Sci., 18, 351 (1974)
P. Aptel, J. Cuny, J. Jozefowicz, G. Morel, and J. Neel, J. Appl. Polym. Sci., 18, 365 (1974)
J. H. Lee and S. C. Kim, Macromolecules, 19, 644 (1986)
J. H. Lee, Ph. D. Thesis, Korea Advanced Institute of Science and Technology, 1986
See, for example, T. Itoh, H. Toya, K. Ishihara, and I. Shinohara, J. Appl. Polym. Sci., 30, 179 (1985)
R. B. Long, Ind. Eng. Chem. Fundamentals, 4, 445 (1965)
D. R. Paul and O. M. Ebra-Lima, J. Appl. Polym. Sci., 14, 2201 (1970)
D. R. Paul and O. M. Ebra-Lima, J. Appl. Polym. Sci., 15, 2199 (1971)
T. Hamaya and S. Yamada, Kobunshi Ronbunshu, 36, 419 (1979)
T. Hamaya and S. Yamada, Kobunshi Ronbunshu, 37, 65 (1980)
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Lee, Y.K., Kim, S.C. Hydrophilic/hydrophobic IPN membranes for the pervaporation of ethanol-water mixture. Polymer Bulletin 20, 261–267 (1988). https://doi.org/10.1007/BF00261979
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DOI: https://doi.org/10.1007/BF00261979