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Copolymerization of ethylene with styrene using the catalyst system composed of Solvay-type TiCl3 and Cp2Ti(CH3)2

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Summary

Copolymerization of ethene and styrene was conducted at 40°C using the catalyst system composed of Solvay type TiCl3 and Cp2Ti(CH3)2. The crude polymer was fractionated with boiling chloroform to obtain 96.4 wt% of insoluble part, which was found to be a random copolymer of ethene and styrene. The copolymer was characterized in detail by DSC, 13C NMR, etc.

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Authors and Affiliations

  1. Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259, Nagatsuta, Midori-ku, 227, Yokohama, Japan

    Kazuo Soga

  2. Department of Polymer Science, Engineering College, Kyungpook National University, 635, Taegu, Korea

    Dong-ho Lee

  3. Oita Research Laboratory, Showa Denko Co. Ltd., 2, Nakanosu, Oaza, 870-01, Oita, Japan

    Hisayoshi Yanagihara

Authors
  1. Kazuo Soga
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  2. Dong-ho Lee
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  3. Hisayoshi Yanagihara
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Soga, K., Lee, Dh. & Yanagihara, H. Copolymerization of ethylene with styrene using the catalyst system composed of Solvay-type TiCl3 and Cp2Ti(CH3)2 . Polymer Bulletin 20, 237–241 (1988). https://doi.org/10.1007/BF00261974

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  • DOI: https://doi.org/10.1007/BF00261974

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