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Synthesis and characterization of polyalkylmethacrylate macromonomers

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Summary

The synthesis of polyalkylmethacrylate macromonomers has been performed anionically by direct deactivation of the carbanionic sites with p-vinyl-or p-isopropenylbenzyl bromide. The characterization of the samples proved that the yields are close to quantitative, and that no side reactions are involved. The method also applies to hydroxyethylmethacrylate and to glycerylmethacrylate, provided the monomers are made aprotic by reversible silylation or acetalization.

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Authors and Affiliations

  1. Centre de Recherches sur les Macromolécules (CNRS), 6, rue Boussingault, 67083, Strasbourg, France

    Pierre Lutz, Patrick Masson, Gérard Beinert & Paul Rempp

Authors
  1. Pierre Lutz
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  2. Patrick Masson
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  3. Gérard Beinert
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  4. Paul Rempp
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Additional information

The authors want to express their deep appreciation to MM. J.Ph. Lamps F. Isel and to Mrs. S. Graff for their technical assistance.

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Lutz, P., Masson, P., Beinert, G. et al. Synthesis and characterization of polyalkylmethacrylate macromonomers. Polymer Bulletin 12, 79–85 (1984). https://doi.org/10.1007/BF00258276

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  • DOI: https://doi.org/10.1007/BF00258276

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