Summary
Poly(vinylidenechloride) powders and films plasticized by different amounts of dibutylsebacate have been investigated by differential thermal analysis (DTA). The molecular mobility of the segments is enhanced by the presence of plasticizer which lowers the glass transition temperature and supports the crystallization behaviour.
Similar content being viewed by others
References
D. Kockott, Kolloid-Z. Z. Polym. 206, 122 (1966)
M. Gordon, J.S. Taylor, J. Appl. Chem. 2, 493 (1952) T.G. Fox, Bull. Am. Phys. Soc. 1, 123 (1956)
H.G. Zachmann, Kolloid-Z. Z. Polym. 189, 67 (1963) A.B. Desai, G.L. Wilkes, J. Polym. Sci. Polym. Symp. 46, 291 (1974) G.L. Wilkes, J. Parlapiano, Polym. Prepr. 17(2), 937 (1976)
Author information
Authors and Affiliations
Additional information
Dedicated to Prof. Dr. G.W. Becker on the occasion of his 60th birthday
Rights and permissions
About this article
Cite this article
Hinrichsen, G., Jahr, H.J. & Springer, H. Crystallization and melting behaviour of plasticized poly(vinylidenechloride). Polymer Bulletin 19, 155–159 (1988). https://doi.org/10.1007/BF00257009
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00257009