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Photopolymerization of 2-(dimethylaminoethyl)methacrylate induced by diacetoxyiodobenzene and bis(trifluoroacetoxy) iodobenzene

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Summary

The title hypervalent iodine compounds are efficient photoinitiators for the polymerization of 2-(dimethylaminoethyl)methacrylate. The polymer is formed in daylight but faster under UV irradiation, with high conversion; its molecular weight 〈Mn〉 is 9×104 daltons. Copolymerization of this monomer with styrene occurs also under similar conditions at a high rate. A free radical mechanism is suggested for these polymerizations.

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Authors and Affiliations

  1. Department of Chemistry, University of Sofia, 1126, Sofia, Bulgaria

    Georgi Georglev & Elena Kamenska

  2. Department of Chemistry, University of Thessaloniki, GR-540 06, Thessaloniki, Greece

    George Karayannidls, Irini Sideridou-Karayannidou & Anastasios Varvoglis

Authors
  1. Georgi Georglev
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  2. Elena Kamenska
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  3. George Karayannidls
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  4. Irini Sideridou-Karayannidou
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  5. Anastasios Varvoglis
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Georglev, G., Kamenska, E., Karayannidls, G. et al. Photopolymerization of 2-(dimethylaminoethyl)methacrylate induced by diacetoxyiodobenzene and bis(trifluoroacetoxy) iodobenzene. Polymer Bulletin 17, 169–174 (1987). https://doi.org/10.1007/BF00256884

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  • DOI: https://doi.org/10.1007/BF00256884

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