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Effect of the complexation with copper(II) on the hydrodynamic behaviour of some polyelectrolytes

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Summary

The complex formation between copper and a number of polyelectrolytes derived from amino-acids was studied by viscosimetry. It was concluded that the complexes involving two side chains of the polymer form between two neighbouring side chains of the same polymeric chain. The effect of copper on the viscosity of the polymer solutions was thus accounted for mainly by changes in the net charge of the polymer and changes in the electrostatic interactions.

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Authors and Affiliations

  1. Laboratoire de Chimie Macromoléculaire, U.A.351 du CNRS, Université des Sciences et Techniques de Lille Flandres Artois, F-59655, Villeneuve d'Ascq Cedex, France

    Abdennbi Lekchiri, Costas Methenitis, Joelle Morcellet & Michel Morcellet

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  1. Abdennbi Lekchiri
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  2. Costas Methenitis
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  3. Joelle Morcellet
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  4. Michel Morcellet
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Lekchiri, A., Methenitis, C., Morcellet, J. et al. Effect of the complexation with copper(II) on the hydrodynamic behaviour of some polyelectrolytes. Polymer Bulletin 17, 119–125 (1987). https://doi.org/10.1007/BF00256876

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  • DOI: https://doi.org/10.1007/BF00256876

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