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Raman spectrum of the high pressure phase of polyethylene

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Summary

The Raman spectrum of the hexagonal high pressure phase of polyethylene was measured at 5.2 kbar and 240 °C, using a hydrostatic high pressure cell. The spectrum is largely identical to that obtained for the melt. This result indicates that the conformational short range order in the hexagonal phase remains melt —like and is not modified by the overall straightening of chains.

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Authors and Affiliations

  1. Institut für Physikalische Chemie der Universität Mainz, D-6500, Mainz, Federal Republic of Germany

    R. Eckel, H. Schwickert & G. R. Strobl

  2. Institut für Physikalische Chemie der Universität Göttingen, D-3400, Göttingen, Federal Republic of Germany

    M. Buback

Authors
  1. R. Eckel
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  2. H. Schwickert
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  3. M. Buback
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  4. G. R. Strobl
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Eckel, R., Schwickert, H., Buback, M. et al. Raman spectrum of the high pressure phase of polyethylene. Polymer Bulletin 6, 559–564 (1982). https://doi.org/10.1007/BF00256379

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  • DOI: https://doi.org/10.1007/BF00256379

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