Skip to main content
SpringerLink
Log in

Solution polymerization of phosphonitrilic chloride trimer in chlorobenzene

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The solution polymerization of phosphonitrilic chloride trimer has been studied by using 50% by weight monomer in Chlorobenzene. Polymerization reactions were conducted at temperatures between 198° and 240°C, and reaction times ranged from 12 to 96 h. Mostly soluble polymer was obtained up to a conversion of 30%. insoluble product was detected only above 240°C and 72 h. of reaction time. Polymers were characterised by intrinsic viscosity and weight average molecular weight, Mw, by light scattering (Zimm plot).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Allcock, H.R. and Best, R.J.; Canadian J. Chem. 42, 447 (1964)

    Google Scholar 

  • Allcock, H.R. and Kugel, R.J.; J. Am. Chem. Soc. 87 4216 (1965)

    Google Scholar 

  • Allen G., Lewis C.J. and Todd, S.M.; Polymer 11,31, 44 (1970)

    Google Scholar 

  • Patat F. and Kollinsky F.; Makromol. Chem. 6, 292 (1951)

    Google Scholar 

  • Retuert J., Ponce S. and Quijada J.R.; Polymer Bull. 1, 653 (1979)

    Google Scholar 

  • Singler R.E. Hagnauer G.L., Schneider N.S., Laliberte B.R. Sacher R.E. and Matton R.W.; J. Polymer Sci., Polym. Chem. Ed. 12, 433 (1974)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento Ingeniería Química, Facultad Ciencias Físicas y Matemáticas, Universidad de Chile, Casilla 2777, Santiago, Chile

    Jaime Retuert, Carlos Aguilera & Francisco Martinez

Authors
  1. Jaime Retuert
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Carlos Aguilera
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Francisco Martinez
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Retuert, J., Aguilera, C. & Martinez, F. Solution polymerization of phosphonitrilic chloride trimer in chlorobenzene. Polymer Bulletin 6, 535–539 (1982). https://doi.org/10.1007/BF00256375

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00256375

Keywords

Search

Navigation