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Intramolecular charge transfer complexes

10. Radical copolymers of methacryloyl β-hydroxyethyl-3,5-dinitrobenzoate with N-(2-hydroxyethyl)carbazolyl acrylate and methacrylate

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Summary

A new acceptor monomer (methacryloyl β-hydroxyethyl-3,5-dinitrobenzoate), having an increased distance between the acceptor group and the double bond, was copolymerized with N-(2-hydroxyethyl)carbazolyl methacrylate and acrylate, respectively. The copolymers are strong intramolecular charge transfer complexes, even at high temperatures. Because the increased distance between the acceptor group and the main chain permits a favourable steric arrangement of the donor and acceptor groups, the intramolecular complexation is independent on copolymer configuration.

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Authors and Affiliations

  1. “Petru Poni” Institute of Macromolecular Chemistry, 6600, Jassy, Romania

    Cristofor I. Simionescu, Virgil Percec & Almeria Natansohn

Authors
  1. Cristofor I. Simionescu
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  2. Virgil Percec
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  3. Almeria Natansohn
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Simionescu, C.I., Percec, V. & Natansohn, A. Intramolecular charge transfer complexes. Polymer Bulletin 3, 535–542 (1980). https://doi.org/10.1007/BF00256296

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  • DOI: https://doi.org/10.1007/BF00256296

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