Summary
Poly [N-(2-hydroxyethyl)carbazolyl methacrylate (HECM)-co-2,4-dinitrophenyl acrylate (DNPA)] and poly [N-(2-hydroxyethyl)carbazolyl acrylate (HECA)-co-DNPA] are intramolecular charge transfer complexes. The intramolecular complexation degree depends on the α-substitution at the monomer double bond. The complex containing two acrylate structural units is the strongest, followed by a methacrylateacrylate copolymer and a methacrylate-methacrylate one, due to the decrease of the coisotactic tendency.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
ITO K., IWASE S., UMEHARA K. and YAMASHITA Y., J. Macromol.Sci.,Chem., A1, 891 (1967)
KADOMA Y., TOIDA T., TAKEDA K., UNO K. and IWAKURA Y., J.Polym.Sci.,Polym.Chem.Ed., 13, 707 (1975)
KELEN T. and TÜDÖS F., J.Macromol.Sci.,Chem., A9, 1 (1975)
KELEN T., TÜDÖS F. and TURCSANYI B., Polym.Bull., 2, 71 (1980)
PERCEC V., NATANSOHN A., BARBOIU V., SIMIONESCU B.C. and GALEA D., Polym.Bull., 2, 505 (1980)
PERCEC V., NATANSOHN A. and SIMIONESCU C.I., J.Macromol.Sci.,Chem., A15, 405 (1980)
SIMIONESCU C.I., PERCEC V. and NATANSOHN A., Polymer, 21, 417 (1980a)
SIMIONESCU C.I., PERCEC V. and NATANSOHN A., Polym.Bull., 2, 435 (1980b)
SIMIONESCU C.I., PERCEC V. and NATANSOHN A., J.Polym.Sci.,Polym.Chem.Ed., submitted
TÜDÖS F., KELEN T., FÖLDES-BEREZHNYKH T. and TURCSA-NYI B., J.Macromol.Sci.,Chem., A10, 1513 (1976)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Simionescu, C.I., Percec, V. & Natansohn, A. Intramolecular charge transfer complexes. Polymer Bulletin 3, 529–533 (1980). https://doi.org/10.1007/BF00256295
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00256295