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Original method for studying the tensile drawing behaviour of polymers by infrared spectroscopy at high-strain rates

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Summary

This communication deals with the description and experimentation of an original method for studying the molecular processes of deformation in polymers by means of infrared spectroscopy under high-speed drawing conditions. The equipment is based on the model of an industrial drawing bench which involves the pulling of a continuous tape or yarn between two sets of feed rolls and draw rolls, in combination with a Fourier Transform Infrared spectrometer.

Preliminary light-polarized measurements concerned with a linear low density polyethylene have been undertaken. Well-resolved infrared spectra are reported for a sample drawn at a take up velocity Vd=39m/min, with a draw ratio λ=7.8.

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Authors and Affiliations

  1. Laboratoire de Spectrochimie Infrarouge et Raman, U.P. CNRS 2641, Université de Lille I, F-59655, Villeneuve d'Ascq Cédex, France

    J. Dupuis, B. Sombret & P. Legrand

  2. Laboratoire de Structure et Propriétés de l'Etat Solide, U.A. CNRS 234, Université de Lille I, F-59655, Villeneuve d'Ascq Cédex, France

    R. Seguela & F. Rietsch

Authors
  1. J. Dupuis
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  2. R. Seguela
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  3. B. Sombret
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  4. P. Legrand
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  5. F. Rietsch
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Dupuis, J., Seguela, R., Sombret, B. et al. Original method for studying the tensile drawing behaviour of polymers by infrared spectroscopy at high-strain rates. Polymer Bulletin 18, 323–327 (1987). https://doi.org/10.1007/BF00256232

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  • DOI: https://doi.org/10.1007/BF00256232

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