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Dimerization of 1-isopropenyl anthracene by TiCl4

Structural study of the dimer

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Summary

1-isopropenyl anthracene was dimerized by reaction with TiCl4 in CH2Cl2 and the structure of the dimer studied by 1H NMR spectroscopy. The spectrum was assigned and is in agreement with simulation. The structure results from the attack of carbocation on carbon 9.

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References

  • BUNEL C., BRIGODIOT M. and MARECHAL E.: J. Macrom. Sci. Chem., (in press)

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Authors and Affiliations

  1. Laboratoire de Chimie Macromoléculaire, Institut National Superieur de Chimie Industrielle de Rouen, B.P. 08, 76130, Mont Saint Aignan, France

    Jean Coudane

  2. Laboratoire de Synthèse Macromoléculaire, Université Pierre et Marie Curie, Tour 44, 1er étage, 4, Place Jussieu, 75230, Paris Cedex 05, France

    Maryvonne Brigodiot & Ernest Marechal

Authors
  1. Jean Coudane
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  2. Maryvonne Brigodiot
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  3. Ernest Marechal
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Coudane, J., Brigodiot, M. & Marechal, E. Dimerization of 1-isopropenyl anthracene by TiCl4 . Polymer Bulletin 1, 469–473 (1979). https://doi.org/10.1007/BF00255710

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  • DOI: https://doi.org/10.1007/BF00255710

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