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Laser spectroscopy of substituted benzophenone used as photo-initiators of vinyl polymerization

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Summary

Nanosecond laser spectroscopy is applied to the determination of the rate constants of several processes involved in the photochemistry of a series of substituted benzophenones. The results allow the initiation of a vinyl monomer polymerization to be discussed and reveal a peculiarity of the benzene/THF system.

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References

  1. MERLIN, A., LOUGNOT, D.J. and FOUASSIER, J.P. : Polymer Bull, in press

  2. TURRO, N.J. : Modern Molecular Photochemistry, The Benjamin/Cummings Publishing Co., Inc., 1978

  3. MERLIN, A. and FOUASSIER, J.P.: Makromol. Chem., 181, 1307 (1980)

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  4. HUTCHINSON, J., LAMBERT, M.C. and LEDWITH, A.: Polymer, 14, 250 (1973)

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Authors and Affiliations

  1. Laboratoire de Photochimie Générale, Equipe de Recherche Associée au CNRS, Ecole Nationale Supérieure de Chimie, 3, rue Alfred Werner, 68093, Mulhouse Cédex, France

    André Merlin, Daniel-Joseph Lougnot & Jean-Pierre Fouassier

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  1. André Merlin
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  2. Daniel-Joseph Lougnot
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  3. Jean-Pierre Fouassier
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Merlin, A., Lougnot, DJ. & Fouassier, JP. Laser spectroscopy of substituted benzophenone used as photo-initiators of vinyl polymerization. Polymer Bulletin 2, 847–853 (1980). https://doi.org/10.1007/BF00255514

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  • DOI: https://doi.org/10.1007/BF00255514

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