Skip to main content
SpringerLink
Log in

Bifunctional initiators

7. Acrylamide polymerization with 4,4′-azo-bis-(4-cyanovaleryl)-bis-(m-chlorobenzoyl) diperoxide as initiator

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

Acrylamide was polymerized by both thermolysis and photolysis of the 4,4′-azo-bis-(4-cyanovaleryl)-bis-(m-chlorobenzoyl) diperoxide as initiator. The molecular weight and the conversion depend on polymerization duration and initiator concentration. The sequential character of the initiator was proved by the two stage polymerization of acrylamide when the obtained molecular weights were twice as compared to those of the one stage process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • ANAND,P.S., STAHL,H.G. and HEITZ,W: Makromol. Chem. 183, 1685 (1982)

    Google Scholar 

  • BILINA,G.S., MATVENTEVA,M.S. and OLIDEKOP,IU.A.: Vysokomol. Soed. 19 555 (1977)

    Google Scholar 

  • GUNESIN,B.Z. and PIIRMA,J.: J. Appl. Polym. Sci. 26 3103 (1981)

    Google Scholar 

  • PIIRMA,J. and CHOU,H.LEE-PET: J. Appl. Polym. Sci. 24 2051 (1979)

    Google Scholar 

  • SHAIKH,A.S., DUMITRIU,S., COMANITA,E and SIMIONESCU,CR.: Polym. Bull. 3 363 (1980)

    Google Scholar 

  • SIMIONESCU,CR., COMANITA,E., DUMITRIU,S. and MACOVEI,I.: Chem. Zvesti 37 693 (1983)

    Google Scholar 

  • SIMIONESCU, CR., KIM GYU SIK, COMANITA, E. and DUMITRIU, S.: Angew. Makromol. Chem. in press.

  • SIMIONESCU, CR., KIM GYU SIK, COMANITA, E. and DUMITRIU, S.: Eur. Polym. J. in press.

Download references

Author information

Authors and Affiliations

  1. Department of Organic and Macromolecular Chemistry, Polytechnic Institute of Jassy, R-6600, Jassy, Romania

    Severian Dumitriu, Eugenia A & Cristofor Simionescu

  2. Chemical Engineering Institute, Hamhîn, D.P.R. Korea

    Kim Gyu Sik

Authors
  1. Kim Gyu Sik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Severian Dumitriu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Eugenia A
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Cristofor Simionescu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sik, K.G., Dumitriu, S., A, E. et al. Bifunctional initiators. Polymer Bulletin 12, 419–425 (1984). https://doi.org/10.1007/BF00255428

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00255428

Keywords

Search

Navigation