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Physico-chemical studies of polymeric carriers: 2. Molecular mass determination of poly(N-vinylpyrrolidone-co-maleic acid) fractions

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Critical interpretation of the various conceptions concerning the problems in characterization of linear polyelectrolyte type polymers containing maleic acid as a comonomer is given. Proper conditions to avoid the fundamental experimental difficulties are proposed. Our conception is supported by molecular light scattering measurements of hydrolysed, fractionated poly (N-vinylpyrrolidone-co-maleic anhydride) samples. It was found that the problems were eliminated by the reduction of the degree of dissociation of carboxyl groups to a minimum value.

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References

  • ALFREY,Jr.,R., BERG,P.W. and MORAWETZ,H.: J.Polym.Sci., 7, 543 (1952)

    Google Scholar 

  • CONIX,A. and SMETS,G.: J.Polym.Sci., 15, 221 (1955)

    Google Scholar 

  • DOTY,P.M. and STEINER,R.F.: J.Polym.Sci., 5, 383 (1950)

    Google Scholar 

  • DUBIN, P.L. and STRAUSS,U.P.: J.Phys.Chem., 74, 2842 (1970)

    Google Scholar 

  • GEORGOEV,G.G., ILIEV,D.V., POPOV,D.V., GEORGIEVA,M.P. and KABAIVANOV,V.S.: Preprints Macro Mainz, Vol.III. 1506 (1979)

  • HEALY,E.M., RAMSLEY,A.O. and NATSIOS,B.A.: J.Appl.Polym.Sci., 16, 37 (1972)

    Google Scholar 

  • KITANO,T., TAGUCHI,A., NODA,I. and NAGASAWA,M.: Macromolecules, 13, 57 (1980)

    Google Scholar 

  • KOTENKO,S.I., LISUNKIN, Yu.I. and POCHINOK, V.Ya.: Pharm.Zh., 1, 19 (1972)

    Google Scholar 

  • KOTIN,L. and NAGASAWA,M.: J.Chem.Phys., 36, 873 (1962)

    Google Scholar 

  • MUTO,N., KOMATSU,T. and NAKAGAWA, T.: Bull.Chem.Soc.Japan, 46, 2711 (1973)

    Google Scholar 

  • NODA, I., TSUGE,T. and NAGASAWA,M.: J.Phys.Chem., 74, 710 (1970)

    Google Scholar 

  • NYKOLAEV,A.F., BONDARENKO,V.M. and SHAKALOVA,N.K.: Vysokomol.Soed., 15B, 737 (1973)

    Google Scholar 

  • OHNO,N., NITTA, K., MAKINO,S. and SUGAI,S.: J.Polym.Sci.Polym.Phys.Ed., 11, 413 (1973)

    Google Scholar 

  • OTH,A. and DOTY,P.: J.Phys.Chem., 56, 43 (1952)

    Google Scholar 

  • SAKURADA,I., SAKAGUCHI,Y. and UEHARA,H.: Kobunshi Kagaku, 27, 82 (1970)

    Google Scholar 

  • SCHULTZ,A.W. and STRAUSS,U.P.: J.Phys.Chem., 76, 1767 (1972)

    Google Scholar 

  • STACEY,K.A.: “Light Scattering in Physical Chemistry” Butterworths, London, 1956

    Google Scholar 

  • TAKAHASHI, A., KATO, T. and NAGASAWA,M.: J.Phys.Chem., 71, 2001 (1967)

    Google Scholar 

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Authors and Affiliations

  1. Central Research Institute of Chemistry of the Hungarian Academy of Sciences, P.O.Box 17, 1525, Budapest, Hungary

    Éva Csákvári, Mária Azori & Ferenc Tüdős

  2. Department of Chemical Technology, Eötvös Loránd University, Muzeum krt 6-8, 1088, Budapest, Hungary

    Ferenc Tüdős

  3. Central Research Institute of Chemistry of the Hungarian Academy of Sciences, P.O.Box 17, 1525, Budapest, Hungary

    Ferenc Tüdős

Authors
  1. Éva Csákvári
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  2. Mária Azori
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  3. Ferenc Tüdős
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Csákvári, É., Azori, M. & Tüdős, F. Physico-chemical studies of polymeric carriers: 2. Molecular mass determination of poly(N-vinylpyrrolidone-co-maleic acid) fractions. Polymer Bulletin 5, 673–677 (1981). https://doi.org/10.1007/BF00255309

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  • DOI: https://doi.org/10.1007/BF00255309

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