Summary
The addition of cyclopentadiene containing a free radical catalyst having a half-life of less than two hrs at reaction temperature, to a solution of N-phenylmaleimide in chlorobenzene at 85°C, or the simultaneous addition of both solutions separately to a reaction tube preheated to 80–195°C, yields a saturated 1∶2 cyclopentadiene-N-phenylmaleimide copolymer, identified by elemental analysis and 1H-NMR spectroscopy, analogous to the formation of a saturated 1∶2 copolymer in the reaction of cyclopentadiene with maleic anhydride under similar conditions.
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Donor-Acceptor Complexes in Copolymerization. LXII. Alternating Diene-Dienophile Copolymers. 14.
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Gaylord, N.G., Martan, M. & Deshpande, A.B. Copolymerization of cyclopentadiene and N-phenylmaleimide. Polymer Bulletin 5, 623–626 (1981). https://doi.org/10.1007/BF00255302
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DOI: https://doi.org/10.1007/BF00255302