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Statistics of the formation of ester on syndiotactic methacrylic anhydride-methacrylic acid copolymers

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Summary

The mode of ring opening during methanolysis of syndiotactic methacrylic anhydride-methacrylic acid copolymers has been studied by statistical calculation, Monte Carlo Simulation,and H-NMR. Significant deviations from random ring opening are found, indicating that the nature of the monomer unit adjacent to the anhydride ring may exert an influence.

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References

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Authors and Affiliations

  1. Lehrstuhl für Makromolekulare Chemie der Technischen Hochschule Aachen, Worringerweg 1, D-5100, Aachen, Federal Republic of Germany

    M. C. Berg-Feld & E. Klesper

  2. Instituto de Macromoleculas, Universidade Federal do Rio de Janeiro, Cidade Universitaria, 21.944, Rio de Janeiro R.J., Brasil

    E. B. Mano

Authors
  1. M. C. Berg-Feld
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  2. E. B. Mano
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  3. E. Klesper
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Berg-Feld, M.C., Mano, E.B. & Klesper, E. Statistics of the formation of ester on syndiotactic methacrylic anhydride-methacrylic acid copolymers. Polymer Bulletin 16, 487–492 (1986). https://doi.org/10.1007/BF00255217

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  • DOI: https://doi.org/10.1007/BF00255217

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