Skip to main content
SpringerLink
Log in

Effect of chemical crosslinking on molecular mobility in swollen polystyrenes

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

Proton relaxation time measurements of chemical crosslinked polystyrenes swollen in protonated and deuterated benzene have been done in order to get informations on the microdynamic behaviour of polystyrene as well as of benzene molecules under the influence of the polymeric network. By means of additional T1d-measurements further evidences for a slow anisotropic motion could be obtained, which cause a T2-“plateau” in the high temperature region. The results are compared with those of MAR-experiments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • BENDLER, J.T. and YARRIS, R.: Macromolecules 17, 650 (1978)

    Google Scholar 

  • DOSKOCILOVA, D., SCHNEIDER, B. and JAKES, J.: J. Magn. Res. 29, 79 (1978)

    Google Scholar 

  • FARRAR, T.C. and BECKER, E.D.: Pulse and Fourier Transform ME: Introduction to Theory and Methods, New York, London. Academic Press 1971

    Google Scholar 

  • GESGHKE, D., KURZE, W. and BRÜCKNER, H.: Faserforsch., Textiltechn./Zeitschr. f. Polymerforsch. 29, 148 (1978)

    Google Scholar 

  • GOTLIB, Yu.Ya., LIFSHITS, M.I. and SHEVELEV, V.A.: Vysokomol. Soed. A 17, 1360 (1975)

    Google Scholar 

  • GOTLIB, Yu.Ya., LIFSHITS, M.I., SHEVELEV, V.A., LISHANSKIJ, P.S. and BALANINA, I.V.: Vysokomol. Soed. A 18, 2299 (1976)

    Google Scholar 

  • GRANDJEAN, J., SILLESCU, H. and WILLENBERG, B.: Die Makromolek. Chem. 178, 1445 (1977)

    Google Scholar 

  • GRONSKI, W. and MURYAMA, N.: Die Makromolek. Chem. 179, 1521 (1978)

    Google Scholar 

  • HEATLEY, F. and WOOD, B.: Polymer 19, 1405 (1978)

    Google Scholar 

  • INOUE, Y. and KANNO, T.: Polym. J. 8, 457 (1976)

    Google Scholar 

  • JEENER, J. and BROEKAERT, P.: Phys. Rev. 157, 232 (1967)

    Google Scholar 

  • JONES, A.A.: J. Polym. Sci. (Polym. Phys. Ed.) 15, 863 (1977)

    Google Scholar 

  • JONES, A.A. and STOCKMAYER, W.H.: J. Polym. Sci. (Polym. Phys. Ed.) 15, 847 (1977)

    Google Scholar 

  • LAUPRETRE, F., NOEL, C. and MONNERIE, L.: J. Polym. Sci. (Polym. Phys. Ed.) 15, 2127 (1977)

    Google Scholar 

  • VALEUR, B., JARRY, J.-P., GENY, F. and MONNERIE, L.: J. Polym. Sci. (Polym. Phys. Ed.) 13, 667 (1975)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physics, Karl-Marx-University, Linnéstrasse 5, 7010, Leipzig, German Democratic Republic

    D. Geschke, K. Pöschel & K. Ludwigs

Authors
  1. D. Geschke
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Pöschel
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Ludwigs
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Geschke, D., Pöschel, K. & Ludwigs, K. Effect of chemical crosslinking on molecular mobility in swollen polystyrenes. Polymer Bulletin 5, 341–346 (1981). https://doi.org/10.1007/BF00255128

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00255128

Keywords

Search

Navigation