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Analysis of the role of complex in the alternating copolymerization of N-vinylpyrrolidone and maleic anhydride

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Summary

Heterogeneous copolymerization of 1-vinyl-2-pyrrolidone (NVP) and maleic anhydride (MA) initiated with AIBN was studied in benzene at 60 °C, at two different total monomer concentrations. The existence of a charge transfer complex between the comonomers has been shown and its equilibrium constant determined. The chemical composition of the copolymer was examined as a function of the initial monomer ratio, and it was found nearly equimolecular in a wide range of relative monomer concentrations. Studying the dependence of the initial rate of copolymerization (W0) on the monomer composition, significant increase in W0 was found at a mole ratio of NVP/MA=1 when 3 mol· dm−3 total monomer concentration was applied. The compositional equation for the NVP/MA copolymerization system was derived with the consideration of the effect of complex.

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Author notes

  1. Flóra Fehérvári

    Present address: Vegyipari Egyesülés, krt 178/186, Budapest, Hungária

Authors and Affiliations

  1. Central Research Institute for Chemistry of the Hungarian Academy of Sciences, P.O.Box 17, H-1525, Budapest, Hungary

    Flóra Fehérvári, Mária Azori, Tamara Földes-Berezsnich & Ferenc Tudős

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  1. Flóra Fehérvári
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  2. Mária Azori
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  3. Tamara Földes-Berezsnich
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  4. Ferenc Tudős
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Fehérvári, F., Azori, M., Földes-Berezsnich, T. et al. Analysis of the role of complex in the alternating copolymerization of N-vinylpyrrolidone and maleic anhydride. Polymer Bulletin 18, 225–232 (1987). https://doi.org/10.1007/BF00255114

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  • DOI: https://doi.org/10.1007/BF00255114

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