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Polymeric bound porphyrines and their precursors

2. Solid phase synthesis of a monosubstituted phthalocyanine

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Summary

The solid state synthesis of a monosubstituted phthalocyanine 6 is described. 4-(4′-Hydroxyphenoxy)-1,2-benzenedicarbonitrile is polymer bound to a chloromethylated macroreticular polystyrene, yielding polymer 3. Reaction of 3 with 4-phenoxy-1,2-benzenedicarbonitrile in the presence of zinc salt results in the formation of covalently bound polymeric phthalocyanine 5. 6 is obtained by cleavage with HBr/acetic acid.

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Authors and Affiliations

  1. Organische und Makromolekulare Chemie, Studiengang Chemie, Universität Bremen, Bibliothekstr. NW 2, D-2800, Bremen 33, Federal Republic of Germany

    Dieter Wöhrle & Gerhard Krawczyk

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  1. Dieter Wöhrle
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  2. Gerhard Krawczyk
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Wöhrle, D., Krawczyk, G. Polymeric bound porphyrines and their precursors. Polymer Bulletin 15, 193–200 (1986). https://doi.org/10.1007/BF00255062

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