Summary
Covalently bound polymeric macrocyclic amines 3b are prepared by two routes. A macroreticular polystyrene is used as carrier. One route proceeds over the polymer bound macrocyclic amine 6b. Furthermore, the analogous low molecular model compounds are prepared. The polymers are able to bind transition metal ions reversibly.
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Wöhrle, D., Nicolaus, V. Synthesis of covalently bound polymeric macrocyclic amines and amides. Polymer Bulletin 15, 185–192 (1986). https://doi.org/10.1007/BF00255061
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DOI: https://doi.org/10.1007/BF00255061