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Canal polymerization

1. 1,3-Butadiyne in perhydrotriphenylene

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Summary

The canal polymerization of 1,3-butadiyne in perhydrotriphenylene (PHTP) and the synthesis of 1,3-butadiyne and perhydrotriphenylene are described. Depending on the experimental method, two types of inclusion compound crystals are obtained. Resonance Raman and uv-visible absorption spectroscopy indicate the backbone to be of the ene-yne type.

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References

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Authors and Affiliations

  1. Materials Science and Technology Division, Mail Stop E549, USA

    B. Jorgensen & R. Liepins

  2. Isotope and Nuclear Chemistry Division, Los Alamos National Laboratory, Mail Stop C346, 87545, Los Alamos, NM, USA

    S. Agnew

Authors
  1. B. Jorgensen
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  2. R. Liepins
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  3. S. Agnew
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Jorgensen, B., Liepins, R. & Agnew, S. Canal polymerization. Polymer Bulletin 16, 263–268 (1986). https://doi.org/10.1007/BF00254995

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  • DOI: https://doi.org/10.1007/BF00254995

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