Summary
The Flory theory of polymer solution was modified by assuming the non-additivity of the number of the degree of external freedom for a binary mixture and applied the modified Flory theory to poly (dimethylsiloxane)-solvent systems. This theory can reproduce the experimental results of the interaction parameter χ and the excess volume of mixing, which the Flory theory failed to reproduce.
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DELMAS,G.PATTERSON,D. and BHATTACHRYTA,S.N.:J.Phys.Chem., 68, 1468(1964)
EICHINGER,B.E. and FLORY,P.J.: Trans.Faraday Soc.,64,2053(1968)
EICHINGER,B.E. and FLORY,P.J.: Trans.Faraday Soc.,64,2061(1968)
EICHINGER,B.E. and FLORY,P.J.: Trans.Faraday Soc.,64,2066(1968)
EICHINGER,B.E. and FLORY,P.J.: Trans.Faraday Soc.,64,2035(1968)
FLORY,P.J.:J.Amer. Chem.Soc.,87,1833(1965)
FLORY,P.J. and HOCKER,H.:Trans.Faraday Soc.,67,2258(1971)
FLORY,P.J. and SHIH,H.:Macromolecules,5,761(1972)
FUJISAWA,K.SHIOMI,T.HAMADA,F. and NAKAJIMA,A.:Polymer J.,submitt ed.
FUJISAWA,K.HAMADA,F. and NAKAJIMA,A.:Reports Progr.Polymer Phys. Japan,19,73(1976).
HAMADA,F.FUJISAWA,K. and NAKAJIMA,A.:Polyner J.,4,316(1973)
HAMADA,F.SHIOMI,T.FUJISAWA,K. and NAKAJIMA,A.:Macromolecules,13,729(1980)
HOCKER,H. and FLORY,P.J.: Trans.Faraday Soc.,67,2270(1971)
HOCKER,H. and FLORY,P.J.: Trans.Faraday Soc.,67,2275(1971)
KUBOTA,K.KIM,Y.KUBO,K. and OGINO,K.:Reports Progr.Polymer Phys. Japan,20,43(1977)
ORWOLL,R.A. and FLORY,P.J.:J.Amer.Soc.,89,6814(1967)
LIN,P.H.C.:Ph.D.Thesis(Washington Univ.,Missoury,1970)
PRIGOGINE,I.TRAPPENIERS,N and MATHOT,V.:Disc. Faraday Soc.,15,193(1953)
PRIGOGINE,I.:The Molecular Theory of Solutions(North-Holland. Amsterdam,1957)
SHIOMI,T.IZUMI,Z,HAMADA,F. and NAKAJIMA,A.:Macromolecules,13,(1980) in press.
SHIOMI,T.FUJISAWA,K.HAMADA,F. and NAKAJIMA,A.:J.Chem.Soc., Faraday Trans.II,76, (1980) in press.
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Fujisawa, K., Shiomi, T., Hamada, F. et al. Theoretical consideration on the number of external degrees of freedom and its application to poly(dimethylsiloxane) solutions. Polymer Bulletin 3, 261–266 (1980). https://doi.org/10.1007/BF00254871
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DOI: https://doi.org/10.1007/BF00254871