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15N NMR spectroscopy 26 coil-helix transition of poly-L-ornithine

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Summary

The coil-helix transition of poly-L-ornithine was studied in water and in a water/methanol mixture (7∶3 by volume) as a function of pH. The 15n NMR chemical shift of N-methylacetamide was measured under analogous conditions and compared with the chemical shifts of poly-L-ornithine to distinguish the influence of the coil-helix transition on the chemical shift from other solvent effects.

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References

  1. Bovey F. A.; Macromol. Reviews 9, 1 (1974)

    Article  CAS  Google Scholar 

  2. Suzuki Y., Inoue Y. and Chujo R.; Biopolymers 16, 2521 (1977

    Article  CAS  Google Scholar 

  3. Lader H.J., Komoroski R.A. and Mandelkern L.; Biopolymers 16, 895 (1977)

    Article  CAS  Google Scholar 

  4. Saito H., Toyokazu O., Masahiko K. and Chikayoshi N.; Biopolymers 18, 1065 (1979)

    Article  CAS  Google Scholar 

  5. Kricheldorf H.R.; Makromol. Chem. 180, 2387 (1979)

    Article  CAS  Google Scholar 

  6. Hull, W.E. and Kricheldorf H.R.; Biopolymers 17, 2427 (1978)

    Article  CAS  Google Scholar 

  7. Katchalski E., Grossfeld J. and Frankel M.; J. Am. Chem. Soc. 70, 2094 (1948)

    Article  CAS  Google Scholar 

  8. Katchalski E. and Spitnik P.; Nature 164, 1092 (1949)

    Article  CAS  Google Scholar 

  9. Dunn M.S. and Rockland L.B.; Advances Protein. Chem. 3, 295 (1947)

    Article  CAS  Google Scholar 

  10. Witanowski M., Stefaniak L. and Janusjewski H.; in “Nitrogen NMR” 1. Ed. Plenum Press, London-New York 1973, p. 164

    Book  Google Scholar 

  11. Cattageno D., Hawkes G.E., and Randall E.W.; J. Chem. Soc. Perkin Trans. 2, 1527 (1976)

    Google Scholar 

  12. Kricheldorf H.R.; Makromol. Chem. 179, 2675 (1978)

    Article  CAS  Google Scholar 

  13. Kricheldorf H.R. and Hull W.E.; Makromol. Chem. 180, 1715 (1979)

    Article  CAS  Google Scholar 

  14. Hull W.E. and Kricheldorf H.R.;Biopolymers in press (Part 20)

Download references

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Authors and Affiliations

  1. Institut für Makromolekulare Chemie der Albert-Ludwigs-Universität, Hermann-Staudinger-Haus, Stefan-Meier-Str. 31, 7800, Freiburg i.Br., Federal Republic of Germany

    Hans R. Kricheldorf

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  1. Hans R. Kricheldorf
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Kricheldorf, H.R. 15N NMR spectroscopy 26 coil-helix transition of poly-L-ornithine. Polymer Bulletin 2, 177–182 (1980). https://doi.org/10.1007/BF00254581

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  • DOI: https://doi.org/10.1007/BF00254581

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