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Synthesis and characterization of nylon-polyisobutylenenylon triblock copolymers

I. Preliminary studies

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Abstract

Nylon-6-polyisobutylene-nylon-6 triblock copolymers have been synthesized by converting telechelic polyisobutylene diols to α, ω-diisocyanate polyisobutylenes and using these macroactivators, in conjunction with strong base, to induce the subsequent anionic polymerization of ε-caprolactam. Pure block copolymer was obtained by suitable sequential extraction. Products were characterized by composition, molecular weight and DSC.

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Wondraczek, R.H., Kennedy, J.P. Synthesis and characterization of nylon-polyisobutylenenylon triblock copolymers. Polymer Bulletin 2, 675–682 (1980). https://doi.org/10.1007/BF00254452

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  • DOI: https://doi.org/10.1007/BF00254452

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