Summary
In this study the changes in the width of the derivative NMR absorption line and the second moment as the function of temperature were investigated for typical urethane elastomers. The polymers crosslinked only by allophanate and biuret bonds as well as modified by the presence of carbon-carbon and ionic bonds were used. It has been found that carbon-carbon and ionic crosslinking bonds cause considerable changes in the glass transition temperature.
Similar content being viewed by others
References
HASSAN,A.M.: CRC Critical Reviews in Macromolecular Sci., 399,(1972)
ZACHMANN,H.G.: J.Polymer Sci. C-43,111 (1973)
RUTKOWSKA,M.: Proceedings of the International Symposium on Macromolecules, MACRO FLORENCE 1980,p.360
RUTKOWSKA,M. and BALAS,A.: J.Appl.Polymer Sci.25,2531 (1980)
RUTKOWSKA,M.: Proceedings of the 27-th International Symposium on Macromolecules, STRASBOURG 1981, p.86
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rutkowska, M., Tekely, P. Effect of space network structure on molecular mobility of urethane elastomers. Polymer Bulletin 7, 481–487 (1982). https://doi.org/10.1007/BF00254374
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00254374