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Effect of space network structure on molecular mobility of urethane elastomers

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Summary

In this study the changes in the width of the derivative NMR absorption line and the second moment as the function of temperature were investigated for typical urethane elastomers. The polymers crosslinked only by allophanate and biuret bonds as well as modified by the presence of carbon-carbon and ionic bonds were used. It has been found that carbon-carbon and ionic crosslinking bonds cause considerable changes in the glass transition temperature.

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Rutkowska, M., Tekely, P. Effect of space network structure on molecular mobility of urethane elastomers. Polymer Bulletin 7, 481–487 (1982). https://doi.org/10.1007/BF00254374

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  • DOI: https://doi.org/10.1007/BF00254374

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