Summary
High resolution carbon−13 nuclear magnetic resonance spectroscopy is used to study the structure of N-amide and N-sulphonamide derivatives of polydiallylamines and shows that these have the poly(3,4-pyrrolidinediylethylene) structure common to most polydiallylamines, not the previously reported poly(3,5-piperidinediylmethylene) structure.
Similar content being viewed by others
References
BRACE, N.O.: J. Org. Chem., 36, 3187 (1971)
BUTLER, G.B. and INGLEY, F.L.: J. Amer. Chem. Soc., 73, 895 (1951)
CRAWSHAW, A. and JONES, A.G.: J. Macromol. Sci. Chem., A6, 65 (1972)
DANIELYAN, V.A., KARSLYAN, S.V. and MATSOYAN, S.G.: Arm. Khim. Zh., 32, 970 (1979)
HAWTHORNE, D.G. and SOLOMON, D.H.: J. Macromol Sci. Chem., A10, 923 (1976)
HAWTHORNE, D.G., JOHNS, S.R., SOLOMON, D.H. and WILLING, R.I.: Aust. J. Chem., 29, 1955 (1976)
HAWTHORNE, D.G., JOHNS, S.R., SOLOMON, D.H. and WILLING, R.I.: Aust. J. Chem., 32, 1155 (1979)
HODGKIN, J.H. and DEMERAC, S.: Advances in Chemistry Series, No. 187, Ions in Polymers, 211 (1980)
HODGKIN, J.H., WILLING, I. and EIBL, R.: J. Polym. Sci. Polym. Chem. Ed., 19, 1239 (1981)
JOHNS, S.R., WILLING, R.I., MIDDLETON, S. and ONG, A.K.: J. Macromol. Sci. Chem., A10, 875 (1976)
LANCASTER, J.E., BACCEI, L., and PANZER, H.P.: J. Polym. Sci. Polym. Lett. Ed. 14, 549 (1976)
MATSOYAN, S.G., POGOSYAN, G.M., DZHAGALYAN, A.O. and MUSHEGAN, A.V.: Polym. Sci. USSR, 4, 1572 (1963)
PHILLIPS, W.D.: J. Chem. Phys., 23, 1363 (1955)
SAYADYAN, A.G., DZHANIKYAN, A.G. and KETIKYAN, M.G.: Arm. Khim. Zh., 30, 433 (1977)
SOLOMON, D.H.: J. Macromol. Sci. Chem., A9, 97 (1975)
UNO, K., TSURUOKA, K. and IWAKURA, Y.: J. Polym. Sci., A1(6), 85 (1968)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hodgkin, J.H., Johns, S.R. & Willing, R.I. Cyclopolymerization of diallylamides and diallylsulphonamides. Polymer Bulletin 7, 353–359 (1982). https://doi.org/10.1007/BF00254290
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00254290