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Dynamic light scattering from dilute and semi-dilute water soluble flexible polymer solutions

Polyacrylamides in the presence of salt

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Summary

Low angle quasi-elastic light scattering has been used to measure translational diffusion coefficients of sodium salts of partly hydrolyzed polyacrylamide samples in the presence of added NaCl.Experiments have been performed both in the dilute concentration range and above the critical concentration for overlapping of polymeric chains.The results reported in the semi-dilute domain are in agreement with the scaling laws predicting the concentration dependence of diffusion coefficients of flexible coils in good solvent condition.

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Authors and Affiliations

  1. ERA 471 du CNRS “Polymères, biopolymères, membranes”, Laboratoire de chimie macromoléculaire, Faculté des Sciences de l'Université de Rouen-Haute Normandie, 76130, Mont Saint Aignan, France

    Guy Muller

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  1. Guy Muller
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Muller, G. Dynamic light scattering from dilute and semi-dilute water soluble flexible polymer solutions. Polymer Bulletin 11, 391–395 (1984). https://doi.org/10.1007/BF00254279

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